2-Furyl methyl ketone
2-Acetylfuran
CAS: 1192-62-7
Molecular Formula: C6H6O2
2-Furyl methyl ketone - Names and Identifiers
| Name | 2-Acetylfuran |
| Synonyms | 2-Acetyfuran 2-Acetylfuran 2-acetyl-fura 2-acetylfurane 1-(2-Furyl)ethanone 1-(2-furanyl)-ethanon 1-(2-Furanyl)ethanone -(2-Furanyl)-ethanone 1-furan-2-yl-ethanone 2-Furyl methyl ketone 1-(2-Furyl)ethan-1-one 1-(furan-2-yl)ethanone 1-(2-furanyl)ethanone (acetylfuran) 1-(2-Furanyl)-ethanone (2-acetylfuran) |
| CAS | 1192-62-7 |
| EINECS | 214-757-1 |
| InChI | InChI=1/C6H6O2/c1-5(7)6-3-2-4-8-6/h2-4H,1H3 |
| InChIKey | IEMMBWWQXVXBEU-UHFFFAOYSA-N |
2-Furyl methyl ketone - Physico-chemical Properties
| Molecular Formula | C6H6O2 |
| Molar Mass | 110.11 |
| Density | 1.098g/mLat 25°C(lit.) |
| Melting Point | 26-28°C(lit.) |
| Boling Point | 67°C10mm Hg(lit.) |
| Flash Point | 160°F |
| JECFA Number | 1503 |
| Water Solubility | Insoluble in water. |
| Vapor Presure | 0.772mmHg at 25°C |
| Appearance | Liquid or Low Melting Solid |
| Specific Gravity | 1.098 |
| Color | light yellow to orange, darkens over time |
| BRN | 107909 |
| Storage Condition | 2-8°C |
| Explosive Limit | 2.1-15.2%(V) |
| Refractive Index | n20/D 1.5070(lit.) |
| Physical and Chemical Properties | density 1.098 |
| Use | Used as raw materials for organic synthesis, pharmaceutical intermediates |
2-Furyl methyl ketone - Risk and Safety
| Hazard Symbols | T - Toxic |
| Risk Codes | R20/21 - Harmful by inhalation and in contact with skin. R25 - Toxic if swallowed R41 - Risk of serious damage to eyes R36/37 - Irritating to eyes and respiratory system. R23/25 - Toxic by inhalation and if swallowed. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S39 - Wear eye / face protection. S38 - In case of insufficient ventilation, wear suitable respiratory equipment. S28A - |
| UN IDs | UN 2811 6.1/PG 2 |
| WGK Germany | 3 |
| RTECS | OB3870000 |
| TSCA | Yes |
| HS Code | 29321900 |
| Hazard Note | Toxic |
| Hazard Class | 6.1 |
| Packing Group | II |
2-Furyl methyl ketone - Upstream Downstream Industry
| Raw Materials | Furan Acetyl Chloride |
2-Furyl methyl ketone - Reference Information
| FEMA | 3163 | 2-FURYL METHYL KETONE |
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Application | 2-acetylfuran can be used as a pharmaceutical synthesis intermediate, and can also be widely used in chemical industry and other fields, it can be extracted from perilla, Perilla frutescens, a plant of perilla genus, is an annual herb. |
| preparation | A preparation method of 2-acetylfuran: 1) extraction of volatile oil: Take dry aerial parts of perilla, after crushing, the volatile oil was extracted by steam distillation for 6h and dried with anhydrous sodium sulfate to obtain the volatile oil. The volatile oil was stored in the fresh-keeping room of refrigerator at 4 ℃ for standby use. The yield of volatile oil was 0.24%. 2) compound separation: 10ml of volatile oil from Perilla frutescens was purified by normal phase silica gel (160-200 mesh) column chromatography. The specification of silica gel column was 50mm × 500mm, with 5 gradient elution, and 5 flow segments were obtained for each gradient, each stream was segmented into 200ml and the solvent was recovered at 35 °c under reduced pressure. The five gradients were n-hexane, n-hexane-ethyl acetate 80:1, n-hexane-ethyl acetate 50:1, n-hexane-ethyl acetate 20:1, and ethyl acetate. 25 fraction sections were obtained, and the fraction section 9 was separated by normal phase silica gel column chromatography to obtain 2.5g of the compound 2-acetylfuran. |
| usage limit | FEMA: baked food, seasoning, meat product, soup, soup, all 20.0mg/kg. Toxic GRAS(FEMA). |
| Use | GB 2760-1996 specifies the permitted use of food flavors. For almonds, nuts, baked goods, brown sugar, bread and other flavors. used as raw materials for organic synthesis, pharmaceutical intermediates |
| production method | is a Friedel-Kraft condensation reaction of furan and acetyl chloride. |
| category | flammable liquid |
| flammability hazard characteristics | flammability; Thermal decomposition releases irritating smoke |
| storage and transportation characteristics | warehouse ventilation and low temperature drying |
| extinguishing agent | dry powder, foam, sand, carbon dioxide, water mist |
Last Update：2024-04-10 22:29:15
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View History
2-Furyl methyl ketone
Aloe capensis, ext.
IMAZOSULFURON SOLUTION
SILICONE DIOXIDE
Ambersep(R) 900 hydroxide form
4-Fluorophenyl methyl sulphide
Aloe capensis, ext.
IMAZOSULFURON SOLUTION
SILICONE DIOXIDE
Ambersep(R) 900 hydroxide form
4-Fluorophenyl methyl sulphide
Raw Materials for 2-Furyl methyl ketone